ТЕОРЕТИЧНЕ ВИВЧЕННЯ СПЕКТРА АТОМА ІТЕРБІЮ НА ОСНОВІ РЕЛЯТИВІСТСЬКОЇ БАГАТОЧАСТИНКОВОЇ ТЕОРІЇ ЗБУРЕНЬ: РІДБЕРГОВІ РЕЗОНАНСИ

V. B. Ternovsky, M. Yu. Gurskaya, A. A. Svinarenko, V. F. Mansarliysky

Анотація


В рамках релятивістської багаточастинкової теорії збурень і узагальненого релятивістського енергетичного підходу проведено теоретичне вивчення характеристик рідбергівських автоіонізаційних резонансів в спектрах атомів лантанідів (ітербію). В якості нульового наближення релятивістської теорії збурень обрані оптимізовані наближення Дірака-Фока і Дірака-Кона- Шема. Оптимізація виконана шляхом введення параметра в обмінні потенціали Фока і Кона-Шема і подальшої мінімізації калібрувально-неінваріантних вкладів в радіаційні ширини атомних рівнів з використанням релятивістських орбітальних базисів, згенерованими відповідними гамільтоніанами нульового наближення, Представлені акуратні теоретичні дані по енергіях і ширинам автоіонізаційних 4f13[2 F7/2]6s2 np[5/2]2 , 4f13 [2 F7/2] 6s2 nf[5/2] резонансів і проведено порівняння з експериментальними даними, отриманими на основі методу лазерної поляризаційної спектроскопії.

Ключові слова


Релятивістська теорія збурень; енергії і ширини резонансів; оптимізоване нульове наближення

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