ТЕОРЕТИЧНЕ ВИВЧЕННЯ СПЕКТРА АТОМА ІТЕРБІЮ НА ОСНОВІ РЕЛЯТИВІСТСЬКОЇ БАГАТОЧАСТИНКОВОЇ ТЕОРІЇ ЗБУРЕНЬ: РІДБЕРГОВІ РЕЗОНАНСИ

Автор(и)

  • V. B. Ternovsky Одеська національна морська академія, Ukraine https://orcid.org/0000-0002-4402-4157
  • M. Yu. Gurskaya Одеський державний екологічний університет, Ukraine
  • A. A. Svinarenko Одеський державний екологічний університет, Ukraine https://orcid.org/0000-0001-7798-6427
  • V. F. Mansarliysky Одеський державний екологічний університет, Ukraine

DOI:

https://doi.org/10.18524/0235-2435.2017.26.126177

Ключові слова:

Релятивістська теорія збурень, енергії і ширини резонансів, оптимізоване нульове наближення

Анотація

В рамках релятивістської багаточастинкової теорії збурень і узагальненого релятивістського енергетичного підходу проведено теоретичне вивчення характеристик рідбергівських автоіонізаційних резонансів в спектрах атомів лантанідів (ітербію). В якості нульового наближення релятивістської теорії збурень обрані оптимізовані наближення Дірака-Фока і Дірака-Кона- Шема. Оптимізація виконана шляхом введення параметра в обмінні потенціали Фока і Кона-Шема і подальшої мінімізації калібрувально-неінваріантних вкладів в радіаційні ширини атомних рівнів з використанням релятивістських орбітальних базисів, згенерованими відповідними гамільтоніанами нульового наближення, Представлені акуратні теоретичні дані по енергіях і ширинам автоіонізаційних 4f13[2 F7/2]6s2 np[5/2]2 , 4f13 [2 F7/2] 6s2 nf[5/2] резонансів і проведено порівняння з експериментальними даними, отриманими на основі методу лазерної поляризаційної спектроскопії.

Біографії авторів

V. B. Ternovsky, Одеська національна морська академія

V. B. Ternovsky

M. Yu. Gurskaya, Одеський державний екологічний університет

M. Yu. Gurskaya

A. A. Svinarenko, Одеський державний екологічний університет

A. A. Svinarenko

V. F. Mansarliysky, Одеський державний екологічний університет

V. F. Mansarliysky

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Glushkov A.V., Khetselius O.Yu., Svinarenko A.A., Prepelitsa G.P., Mischenko E.V., The Green’s functions and density functional approach to vibrational structure in the photoelectron spectra for molecules// AIP Conf. Proceedings.-2010.-Vol.1290.-P. 263-268.

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Khetselius O. Yu.,Florko T. A.,Nikola L., Svinarenko A., Serga I., Tkach T.,

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